Technetium (Tc) is a transition metal with a unique status: it is the element with the lowest atomic number (43) that has no stable isotopes. For this reason, it practically does not occur naturally on Earth. Its name, derived from the Greek tekhnetos, meaning "artificial," pays homage to its origin, as it was the first synthetically produced element.
For decades, chemists knew that an element must exist between molybdenum (atomic number 42) and ruthenium (number 44), but they couldn't find it in nature. It was like a missing piece in the puzzle of the periodic table. That element was technetium (Tc), the first to be produced artificially before being identified naturally.
Its name comes from the Greek technetos, meaning "artificial," and not by chance: it was the first element created in a laboratory before being found in natural traces. Its discovery in 1937 by Carlo Perrier and Emilio Segrè marked a milestone in modern chemistry, demonstrating that the periodic table could be completed not only through exploration but also through nuclear engineering.
Technetium's instability is due to its nuclear structure. Its isotopes have an imbalance of protons and neutrons that makes them inherently radioactive, decaying into other elements. The most common and longest-lived isotope, technetium-99, has a half-life of 211,000 years, which, in geological terms, is extremely short. Any technetium that might have existed on early Earth would have decayed long ago. The small amount found in nature, in fact, is produced as a byproduct of the spontaneous fission of heavy elements like uranium.
Today, technetium is obtained primarily as a byproduct in nuclear reactors. When uranium-235 fissions, it generates a variety of products, including technetium-99, the most widely used isotope. This is extracted from spent fuel rods using specialized chemical processes.
Tc-99 has a half-life of over 200,000 years and emits beta radiation, making it useful in nuclear medicine. In the form of pertechnetate (TcO₄⁻), it is used in gamma ray imaging to visualize organs such as the heart, liver, and bones, thanks to its ability to concentrate in specific tissues without causing significant damage.
Technetium is a silvery metal, similar in appearance to platinum, but much rarer. It has no known biological function and must be handled with caution due to its radioactivity. Despite this, its usefulness in medical diagnostics makes it one of the most widely used radioisotopes in hospitals worldwide.
Its use in corrosion inhibitors for steel systems has also been investigated, although its radioactivity limits its application outside controlled settings.
Technetium represents a scientific paradox: a metal that "does not exist" on Earth in a stable form, yet has been essential to modern medicine and to understanding the nuclear processes of the universe. Its history is a reminder that the periodic table is not just a list of elements, but a narrative of discovery, ingenuity, and exploration beyond the visible.